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Hydrations of Alkenes: Acid-Catalyzed, Oxymercuration, and Hydroboration Oxidation
The acid-catalyzed hydration and oxymercuration-demercuration add the OH in Markovnikov fashion, whereas the hydroboration-oxidation is an anti Markovnikov addtion. Unlike acid-catalyzed hydration, there are nor rearrangements in oxymercuration-demercuration reactions.